Hydroformylation reactions of the trans-Mo(CO)4(p-C5NH4SO3NA)2 complex in biphasic medium

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dc.contributor.authorSuárez B., Trino
dc.contributor.authorFontal, Bernardo
dc.contributor.authorZambrano, Ghery
dc.contributor.authorReyes, Marisela del C.
dc.contributor.authorBellandi, Fernando
dc.contributor.authorContreras, Ricardo Rafael
dc.contributor.authorDíaz, Juan C.
dc.contributor.authorCancines, Pedro I.
dc.contributor.authorFonseca V., Yuraima J.
dc.contributor.authorRomero C., Isolda
dc.date.accessioned2011-08-12T01:41:12Z
dc.date.available2011-08-12T01:41:12Z
dc.date.issued2008-10-12
dc.descriptionArtículo Publicado en React.Kinet.Catal.Lett. Vol. 94, No. 1, 27−34 (2008)es_VE
dc.description.abstractTrans-bis(sodium pyridine-p-sulphonate)tetracarbonylmolybdenum(0) complex, (trans-Mo(CO)4(p-PySO3Na)2, (1)) was used as a catalytic precursor for the 1- hexene hydroformylation reaction, in biphasic toluene/water medium (T = 100ºC, syngas total pressure = 600 psi, pH2/pCO = 1). Complex (1) showed good activity favoring the linear aldehyde. Likewise as other organic olefin substrates and with synthetic and real naphtha, good conversions to oxygenated products were obtained.es_VE
dc.description.emailsuarez@ula.vees_VE
dc.description.emailfontal@ula.ve, bfontal@hotmail.comes_VE
dc.description.emailreyes@ula.vees_VE
dc.description.emailbellandi@ula.vees_VE
dc.description.emailricardo@ula.vees_VE
dc.description.emailcancines@ula.vees_VE
dc.description.emailfonsy@ula.vees_VE
dc.description.emailirc@cantv.netes_VE
dc.identifier.urihttp://www.saber.ula.ve/handle/123456789/33632
dc.language.isoenes_VE
dc.publisherAkadémiai Kiadó, Budapest and Springer, Dordrechtes_VE
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.licensehttp://creativecommons.org/licenses/by-nc-sa/3.0/ve/
dc.subjectBiphasic catalysises_VE
dc.subjectHydroformylationes_VE
dc.subjectNaphthaes_VE
dc.subjectMolybdenum complexes_VE
dc.subject.facultadFacultad de Cienciases_VE
dc.subject.thematiccategoryQuímicaes_VE
dc.subject.tipoArtículoses_VE
dc.subject.unidadinvLaboratorio de Organometálicoses_VE
dc.titleHydroformylation reactions of the trans-Mo(CO)4(p-C5NH4SO3NA)2 complex in biphasic mediumes_VE
dc.typeinfo:eu-repo/semantics/article
dc.type.mediaTextoes_VE

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